21 Best Free PHP and MySQL E-Books for Programmers

1) Learn PHP, MySQL, CSS, JavaScript and HTML5 

2) PHP 5 Power Programming

3) Beginning Php5 Apache And Mysql Web Development

4) PHP5 And MySQL Bible

5) PHP and MySQL Web Development All in One

6) PHP 6/MySQL Programming for Absolute Beginner

7) PHP 6 Fast and Easy Web Development

8) PHP: The Basics

9) MySQL PHP Database Applications

10) Head First! PHP and MySQL

11) PHP6 and MySQL

12) Professional Lamp Linux Apache Mysql Php5

13) PHP the right way

14) The Oracle PHP Cookbook

15) Practical PHP Testing

16) Code Bright for Laravel PHP

17) Practical PHP Programming

18) PHP Programming

19) PHP Security Guide

20) Advanced CakePHP Tips

21) PHP Programming

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Free ebooks for professionals

https://github.com/vhf/free-programming-books/blob/master/free-programming-books.md#professional-development